Dry adhesive holds in extreme cold and strengthens in heat

The research, which builds on earlier development of a single-sided dry adhesive tape based on vertically aligned carbon nanotubes, is published in the journal Nature Communications. As far as the researchers know, no other dry adhesive is capable of working at such temperature extremes.

Liming Dai, professor of macromolecular science and engineering at Case Western Reserve and an author of the study teamed with Ming Xu, a senior research associate at Case School of Engineering and visiting scholar from Huazhong University of Science and Technology; Feng Du, senior research associate in Case Western Reserve's Department of Macromolecular Science and Engineering; and Sabyasachi Ganguli and Ajit Roy, of the Materials and Manufacturing Directorate, Air Force Research Laboratory.

Vertically aligned carbon nanotubes with tops bundled into nodes replicate the microscopic hairs on the foot of the wall-walking reptile and remain stable from -320ºF to 1,832ºF, the scientists say.

"When you have aligned nanotubes with bundled tops penetrating into the cavities of the surface, you generate sufficient van der Waal's forces to hold," Xu said. "The dry adhesive doesn't lose adhesion as it cools because the surface doesn't change. But when you heat the surface, the surface becomes rougher, physically locking the nanotubes in place, leading to stronger adhesion as temperatures increase."

Because of the adhesive remains useful over such a wide range of temperatures, the inventors say it is ideally suited for use in space, where the shade can be frigid and exposure to the sun blazing hot.

In addition to range, the bonding agent offers properties that could add to its utility. The adhesive conducts heat and electricity, and these properties also increase with temperature. "When applied as a double-sided sticky tape, the adhesive can be used to link electrical components together and also for electrical and thermal management," Roy said.

"This adhesive can thus be used as connecting materials to enhance the performance of electronics at high temperatures," Dai said. "At room temperature, the double-sided carbon nanotube tape held as strongly as commercial tape on various rough surfaces, including paper, wood, plastic films and painted walls, showing potential use as conducting adhesives in home appliances and wall-climbing robots."

In testing, a double-sided tape made with the carbon nanotubes (CNTs) applied between two layers of copper foil had an adhesive strength of about 37 newtons per cm-2 at room temperature, about the same as a commercial double-sided sticky tape.

Unlike the commercial tape, which loses adhesion as it freezes or is heated, the CNT adhesive maintained its strength down to -320ºF. The adhesive strength more than doubled at 785ºF and was about six times as strong at 1891ºF.

Surprised by the increasing adhesive strength, the researchers used a scanning electron microscope to search for the cause. They found that, as the bundled nodes penetrate the surface cavities, the flexible nanotubes no longer remain vertically aligned but collapse into web-like structures. The action appears to enhance the van der Waal's forces due to an increased contact surface area with the collapsed nanotubes.

Looking further, the researchers found that as the temperature increased above 392ºF, the surface of the copper foil became increasingly rough. The bundled ends and collapsed nanotubes appear to penetrate deeper into the heat-induced irregularities in the surface, increasing adhesion. The researchers dub this adhesion mechanism "nano-interlocking."

The adhesive held strong during hundreds of temperature transition cycles between ambient temperature and -320ºF then up to 1891ºF and between the cold extreme and ambient temperature.

Copper foil, which was used for many of the tests to demonstrate the potential for thermal management, is not unique. The surface of many other materials, including polymer films and other metal foils, roughen when heat is applied, making them good targets for this kind of adhesive, the team suggests.